Product ID:WATER STANDARD KIT-A PHENOL MIXTURE, 48807
MSDS Date:01/01/1987
FSC:6850
NIIN:00N018228
Kit Part:Y
MSDS Number: BMDZY

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

PHENOL, 2,4,6-TRICHLORO-; (2,4,6-TRICHLOROPHENOL)

CAS: 88-06-2

RTECS: SN1575000

Fraction By Weight: 0.15%

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

M-CRESOL, 4-CHLORO-; (CHLOROCRESOL

CAS: 59-50-7

RTECS: GO7100000

Fraction By Weight: 0.25%

OSHA PEL 5 PPM, S (AS CRESOL)

ACGIH TLV: 5 PPM, S (AS CRESOL)

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PHENOL, O-CHLORO; (2-CHLOROPHENOL)

CAS: 95-57-8

RTECS: SK2625000

Fraction By Weight: 0.05%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

PHENOL, O-NITRO-; (2-NITROPHENOL)

CAS: 88-75-5

RTECS: SM2100000

Fraction By Weight: 0.05%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

PHENOL, P-NITRO-; (4-NITROPHENOL)

CAS: 100-02-7

RTECS: SM2275000

Fraction By Weight: 0.25%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

O-CRESOL, 4,6-DINITRO-; (DINITRO-O-CRESOL).

CAS: 534-52-1

RTECS: GO9625000

Fraction By Weight: 0.25%

OSHA PEL 0.2 MG/M3, S

ACGIH TLV: 0.2 MG/M3, S

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

PHENOL, PENTACHLORO-; (PENTACHLOROPHENOL).

CAS: 87-86-5

RTECS: SM6300000

Fraction By Weight: 0.25%

OSHA PEL 0.5 MG/M3, S

ACGIH TLV: 0.5 MG/M3, S

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

(ORAL,RAT)384 MG/KG.

CAS: 108-95-2

RTECS: SJ3325000

Fraction By Weight: 0.05%

OSHA PEL 5 PPM, S

ACGIH TLV: 5 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHANE, DICHLORO-; (METHYLENE CHLORIDE).

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 98.45%

OSHA PEL 500 PPM;1000 PPM, C

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

STRESS THE CARDIOVASCULAR SYSTEM DUE TO INCREASED

RTECS: 9999999ZZ

BEEN SHOWN TO PRODUCE SIGNIFICANT INCREASE IN

RTECS: 9999999ZZ

DECOMPOSE TO FORM HYDROGEN CHLORIDE GAS AND

RTECS: 9999999ZZ

PHENOL, 2,4-DINITRO-; (2,4-DINITROPHENOL)

CAS: 51-28-5

RTECS: SL2800000

Fraction By Weight: 0.15%

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

2,4-XYLENOL; (2,4-DIMETHYLPHENOL)

CAS: 105-67-9

RTECS: ZE5600000

Fraction By Weight: 0.05%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

PHENOL, 2,4-DICHLORO-; (2,4-DICHLOROPHENOL)

CAS: 120-83-2

RTECS: SK8575000

Fraction By Weight: 0.05%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRODUCED
SENSITIZATION OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD
HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G.,EPINEPHRINE) MAY
BE CONTRAINDICATED EXCEPT FOR LIFE- SUSTAINING USES IN HUMANS
ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS . MAY BE FATAL IF
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:TRICHLOROPHENOL (2,4,6):GROUP
2(NTP);METHYLENE CHLORIDE IARC GROUP 2B; NTP GROUP 2.
Effects of Overexposure:HLTH HAZ:INHALED. HARMFUL IF SWALLOWED.
CONTAINS MATL KNOWN TO STATE OF CAL TO CAUSE CANCER. LACHRIMATION.
IRRITS SKIN, DERM, HDCH, DIZZ, NARCOSIS, LIVER/KIDNEY DMG. SEVERAL
CHRONIC INHAL STUDIES REPO RTED BY NIOSH REVEALED TEST ANIMALS
EXPSD TO METHYLENE CHLORIDE CONCS AS HIGH AS 10000PPM SHOWED SLIGHT
LIVER(SUPP DATA)
Medical Cond Aggravated by Exposure:INCREASED SENSITIVITY OF THE HEART
TO ADRENALIN MAY BE CAUSED BY OVEREXPOSURE TO METHYLENE CHLORIDE.

First Aid:EYE:FLUSH W/WATER FOR AT LEAST 15 MIN. SKIN:PROMPTLY WASH
W/MILD SOAP & LG VOLS OF WATER. REMOVE CONTAMD CLTHG. INHAL:IMMED
MOVE TO FRESH AIR. GIVE O2 IF BRTHG LABORED. IF BRTHG STOPS, GIVE
ARTF RESP. CALL MD. NEVER GIVE ADRENALIN FOLLOWING EXPOS.
INGEST:NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. NEVER TRY TO
MAKE UNCON PERSON VOMIT. DO NOT INDUCE VOMITING. IMMED CALL MD.

Extinguishing Media:WATER, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE-DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THE FOLLOWING TOXIC VAPORS ARE FORMED
WHEN THIS MATERIAL IS HEATED TO DECOMPOSITION:HYDROGEN CHLORIDE &
PHOSGENE.

Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA.
METHYLENE CHLORIDE VAPORS ARE HEAVIER THAN AIR & WILL COLLECT IN
LOW AREAS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN SEALED CONTAINER IN COOL, DRY
LOCATION. POSSIBLE CANCER HAZARD.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICIN OF
ARC WELDING, OPEN FLAMES/HOT SURFS. HEAT &/OR UV RADIATION MAY
CAUSE FORMATION OF HCL &/OR PHOSGENE . MATL/VAPS WHEN IN CNTCT
W/FLAMES, HOT GLOWING SURFS/ELEC ARCS CAN (ING 15)

Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATORY PROTECTION.
WEAR NIOSH/MSHA APPROVED FACE MASK W/ORGANIC VAPOR CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP:& KIDNEY CHGS. METHYLENE CHLORIDE HAS BEEN SHOWN TO
INCR RATE OF SPONTANEOUSLY OCCURING MALIGNANT TUMORS IN ONE STRAIN
OF LAB MICE/BENIGN TUMORS IN LAB RATS. METHYLENE CHLORIDE IS NOT
BELIEVED TO POSE A CARCIN RISK TO MAN WHEN HANDLED AS RECOMM.
METHYLENE CHLORIDE IS METABOLIZED TO CO & CAN (ING 13)

HCC:T4
Boiling Pt:B.P. Text:104F,40C
Melt/Freeze Pt:M.P/F.P Text:-143F,-97C
Vapor Pres:349
Vapor Density:2.93
Spec Gravity:1.320 G/ML
Evaporation Rate & Reference:0.71 (ETHER = 1).
Solubility in Water:1.6%
Appearance and Odor:CLEAR, COLORLESS LIQUID, ETHER-LIKE ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG BASES, OXIDIZING AGENTS.
Hazardous Decomposition Products:HYDROGEN CHLORIDE & PHOSGENE.
Conditions to Avoid Polymerization:LIQUID OXYGEN/OTHER STRONG OXIDANTS
MAY FORM EXPLOSIVE MIXTURES W/METHYLENE CHLORIDE.

Waste Disposal Methods:COMPLY W/ALL APPLICABLE FEDERAL, STATE AND LOCAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.